|本期目录/Table of Contents|

[1]孙进桃,陈 琪,郭元伟.非平衡等离子体重整甲烷的动力学机理[J].燃烧科学与技术,2018,(02):104-110.[doi:10.11715/rskxjs.R201704067]
 Sun Jintao,Chen Qi,Guo Yuanwei.Kinetic Mechanism of Methane Conversion Assisted by Non-Equilibrium Plasma[J].Journal of Combustion Science and Technology,2018,(02):104-110.[doi:10.11715/rskxjs.R201704067]
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非平衡等离子体重整甲烷的动力学机理()
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《燃烧科学与技术》[ISSN:1006-8740/CN:12-1240/TK]

卷:
期数:
2018年02
页码:
104-110
栏目:
出版日期:
2018-04-15

文章信息/Info

Title:
Kinetic Mechanism of Methane Conversion Assisted by Non-Equilibrium Plasma
文章编号:
1006-8740(2018)02-0104-07
作者:
孙进桃陈 琪郭元伟
北京交通大学机械与电子控制工程学院,北京 100044
Author(s):
Sun JintaoChen QiGuo Yuanwei
School of Mechanical,Electronic and Control Engineering,Beijing Jiaotong University,Beijing 100044,China
关键词:
甲烷非平衡等离子体低碳烃反应机理
Keywords:
methanenon-equilibrium plasmalight carbon hydrocarbonsreaction mechanism
分类号:
TE646
DOI:
10.11715/rskxjs.R201704067
文献标志码:
A
摘要:
采用数值模拟和实验研究相结合的方法研究了非平衡等离子体重整甲烷的动力学过程,结合实验数据,建立了低温下非平衡等离子体重整甲烷的详细反应动力学机理.与实验结果相比,该动力学机理可准确预测甲烷 重整反应中甲烷转化率及各产物选择性的变化趋势.通过模拟研究了甲烷的放电特性,根据建立的机理研究获得反应路径并对积碳进行了深入分析,为等离子体与催化剂协同甲烷重整反应的机理研究奠定基础.
Abstract:
A combination of simulation and experimental research method is used to study the kinetic process of plasma assisted methane reforming.Based on the experimental data,a detailed kinetic mechanism of plasma reforming of methane at low temperature was established.Compared with the experimental results,the kinetic mechanism can accurately predict the methane conversion rate and the change trend of each product in methane reforming reaction.The discharge characteristics of methane were studied by simulation,the reaction pathway diagram was obtained,and then the carbon deposition was deeply analyzed based on the mechanism.This study laid a foundation for reforming reaction mechanism and catalyst catalytic methane plasma.

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备注/Memo

备注/Memo:
收稿日期:2017-04-28. 基金项目:国家自然科学基金资助项目(51376021). 作者简介:孙进桃(1989— ),男,博士研究生,17116348@bjtu.edu.cn. 通讯作者:陈 琪,女,博士,副教授,qchen@bjtu.edu.cn.
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